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欧盟委员会发布CLP附件VI修订草案,54个物质统一分类受影响

来源 瑞旭集团 作者

ECHA风险评估委员会就引入或更新某些物质的统一分类和标签发布意见,并在发布修订以前,向成员国和利益相关者征集意见。本次拟采纳意见的物质有54个,清单见附表。

欧盟委员会曾收到利益相关方对1,4-苯二胺、N,N'-混合Ph、甲苯基衍生物、二丁基氧化锡的科学评估提出的质疑。经评估,额外的信息不足以质疑其科学评估。因此,引入有关物质的统一分类和标签是适当的。

另外,数据表明铅块在水中的溶解度低于铅粉,根据法规(EC)1272/2008附件I第4部分的计算得出的铅块分类不够严格。因此,就M因子而言,修改铅粉已有的水生毒性分类是合适的,并对铅块引入不同的水生毒性分类。

关于甲基丙烯酸甲酯的呼吸道致敏物分类,碳酸锂、氯化锂和氢氧化锂作为生殖毒性物质的分类,委员会也收到了利益相关方的补充信息。由于新信息还需进一步评估,上述4种物质在现阶段不应进行统一的分类和标签。

此次分类修订,欧盟也给予了供应商一段过渡期,用来调整产品的标签和包装,并根据现有的监管要求销售现有库存。供应商也可以在本条例适用日期前自愿应用新的分类。本法规将会在《欧盟官方公报》上公布后第20天生效,并将在生效后的18个月后开始适用。

附表:

序号

物质名称

1. 

benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate

2. 

benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

3. 

reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate (1:1)

4. 

reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

5. 

4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol; bisphenol AF

6. 

cinnamaldehyde; 3-phenylprop-2-enal; cinnamic aldehyde; cinnamal [1], (2E)-3-phenylprop-2-enal [2]

7. 

benfluralin (ISO); N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine

8. 

3,3'-dimethylbiphenyl-4,4'-diyl diisocyanate

9. 

foramsulfuron (ISO); 2-{[(4,6-dimethoxypyrimidin-2-yl)carbamoyl]sulfamoyl}-4-formamido-N,N-dimethylbenzamide; 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-dimethylcarbamoyl-5-formamidophenylsulfonyl)urea

10. 

ethyl acrylate

11. 

methyl acrylate; methyl propenoate  

12. 

methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate

13. 

transfluthrin (ISO); 2,3,5,6-tetrafluorobenzyl (1R,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

14. 

allyl methacrylate; 2-methyl-2-propenoic acid 2-propenyl ester

15. 

mepiquat chloride (ISO); 1,1-dimethylpiperidinium chloride

16. 

triethylamine

17. 

di-n-butylamine

18. 

4-nitrosomorpholin

19. 

difenoconazole (ISO); 1-({2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole; 3-chloro-4-[(2RS,4RS;2RS,4SR)-4-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-2-yl]phenyl 4-chlorophenyl ether

20. 

N,N-dimethyl-p-toluidine

21. 

potassium chlorate

22. 

sodium chlorate

23. 

reaction mass of 1-(2,3-epoxypropoxy)-2,2-bis ((2,3-epoxypropoxy)methyl) butane and 1-(2,3-epoxypropoxy)-2-((2,3-epoxypropoxy)methyl)-2-hydroxymethyl butane

24. 

metribuzin (ISO); 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one; 4-amino-4,5-dihydro-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5-one

25. 

lithium carbonate [1] lithium chloride [2] lithium hydroxide [3]

26. 

dimethyl propylphosphonate

27. 

dibutyltin maleate

28. 

dibutyltin oxide

29. 

clothianidin (ISO); (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine

30. 

cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide

31. 

nonylphenol, branched and linear, ethoxylated (with average molecular weight < 352 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

32. 

nonylphenol, branched and linear, ethoxylated (with 352 g/mol ≤ average molecular weight < 704 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

33. 

nonylphenol, branched and linear, ethoxylated (with 704 g/mol ≤ average molecular weight ≤ 1540 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

34. 

1-phenylethan-1-one (1-phenylethylidene)hydrazone

35. 

9-[2-(ethoxycarbonyl)phenyl]-3,6-bis(ethylamino)-2,7-dimethylxanthylium chloride; Basic Red 1

36. 

picolinafen (ISO); N-(4-fluorophenyl)-6-[3-(trifluoromethyl)phenoxy]pyridine-2-carboxamide; 4′-fluoro-6-[(α,α,α-trifluoro-m-tolyl)oxy]picolinanilide

37. 

diuron (ISO); 3-(3,4-dichlorophenyl)-1,1-dimethylurea

38. 

diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

39. 

hydrogen sulphide, hydrogen sulfide

40. 

benzyl alcohol

41. 

resorcinol; 1,3-benzenediol

42. 

2,2',6,6'-tetrabromo-4,4'-isopropylidenediphenol; tetrabromobisphenol-A

43. 

a reassessment at the request of the Commission to review the harmonised classification of lead (environment) -

44. 

2,2'-[[3-methyl-4-[(4-nitrophenyl)azo]phenyl]imino]bisethanol

45. 

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-ol

46. 

1,4-Benzenediamine, N,N'-mixed Ph and tolyl derivs.; Reaction mass of N-phenyl,N’-o-tolyl-phenylene diamine, N,N’-diphenyl-p-phenylene diamine and N,N’-di-o-tolyl-phenylene diamine

47. 

tetramethylene dimethacrylate

48. 

7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate

49. 

2,2'-ethylenedioxydiethyl dimethacrylate

50. 

bifenox (ISO); methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate

51. 

4-methylimidazole

52. 

sulfur dioxide

53. 

1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one

54. 

benalaxyl (ISO); methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate

 

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